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21.
The eigenvalues of a differential operator on a Hilbert-Pόlya space are determined. It is shown that these eigenvalues are exactly the nontrivial zeros of the Riemann $\zeta$-function. Moreover, their corresponding multiplicities are the same. 相似文献
22.
Tong Ge Yonghua Lu Kecheng Lu Yunhai Wang Xin Liu Zhanglin Cheng Yi Chen Oliver Deussen Baoquan Chen 《显形杂志》2020,23(3):523-537
In the field of evolutionary genome analysis, biologists seek to identify important genes or chromosome regions by comparing phylogenetic trees and analyzing the mutation at which locus might affect phenotypic traits. Unfortunately, the tree comparison and accompanying analysis are often performed manually. In this paper, we characterize the workflow of evolutionary genome analysis and present a task analysis for the fundamental questions asked by biologists during the analysis procedure. We propose two algorithms to enable quantitative tree comparison. One is to measure the differences between corresponding leaf nodes on two trees, and the other is to compute the classification inconsistency of each leaf node by comparing tree structure with a given biological classification. Configuring with the obtained difference and inconsistency, we present a visual analysis system, visual comparison of phylogenetic trees for evolutionary genome analysis, which not only enables biologists to intuitively explore trees but also identify locus which affects their traits by comparing SNP variants of selected leaf nodes. We conclude with case studies from two biologists who used our system to augment their previous manual analysis workflow and demonstrate that our system can reveal more insight. 相似文献
23.
Wang Ruijie Zheng Jinyun Feng Xiangming Yao Ge Niu Huiting Liu Qingyi Chen Weihua 《Journal of Solid State Electrochemistry》2020,24(3):511-519
Journal of Solid State Electrochemistry - LiMnPO4 has been attracting attention for high energy density (701 Wh kg−1) and excellent safety. However, LiMnPO4 suffers from the... 相似文献
24.
Dr. Huixin Fan Prof. Chensheng Lin Kaichuang Chen Dr. Guang Peng Dr. Bingxuan Li Prof. Ge Zhang Prof. Xifa Long Prof. Ning Ye 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(13):5306-5310
An ammonium-containing metal iodate fluoride compound, (NH4)Bi2(IO3)2F5, featuring a two-dimensional double-layered framework constructed by [BiO2F5]6− and [BiO4F4]9− polyhedra, as well as [IO3]− groups, was successfully synthesized. The well-ordered alignment of these SHG-active units leads to an extraordinary strong SHG response of 9.2 times that of KDP. Moreover, this compound possesses a large birefringence (Δn=0.0690 at 589.3 nm), a wide energy band gap (Eg=3.88 eV), and a high laser damage threshold (LDT; 40.2×AgGaS2). In particular, thermochromic behavior was observed for the first time in this type of compound. Such multifunctional crystals will expand the application of nonlinear optical materials. 相似文献
25.
26.
Mengyuan Ge Guangwen Li Zibo Ni Ning Liu Yushan Liu Yuzhou Liu 《Journal of polymer science. Part A, Polymer chemistry》2020,58(21):3009-3017
Utilizing collective forces between reactant and multiple catalyst molecules has been unprecedented due to the difficulty in realizing high order catalysis. Inspired by the power of collective forces in enzymes and organic catalysts, herein we report a rare example of high order catalysis for ring opening reaction (ROR) of strained rings by methanol. ROR is an important way to produce various polysiloxanes, but usually suffers from serious side reactions especially at high conversion, and currently there is a need to design new reaction pathway to achieve low molecular dispersity. In our study, the judiciously designed strained spiral cyclosiloxanes enable a high order catalysis by methanol, and this new methodology leads to a cyclic polysiloxane with high molecular weight and low dispersity even at full conversion of reactants. Kinetic study indicates an extremely unusual high-order reaction involving multiple methanol molecules per reaction, also confirmed by quantum calculation which reveals the presence of zwitterionic ions stabilized by collecting force of hydrogen bonds by methanol molecules. The inherent driving force for this unusual phenomenon is dominated by enthalpy stabilization of the reactive intermediates through hydrogen bonding. The selective formation of Si O Si bonds, instead of silanol products, reflects the power of scientific design. 相似文献
27.
Ruochun Zhang Yulin Qi Chao Ma Jinfeng Ge Qiaozhuan Hu Fu-Jun Yue Si-Liang Li Dietrich A. Volmer 《Molecules (Basel, Switzerland)》2021,26(1)
Lignin is the second most abundant natural biopolymer, which is a potential alternative to conventional fossil fuels. It is also a promising material for the recovery of valuable chemicals such as aromatic compounds as well as an important biomarker for terrestrial organic matter. Lignin is currently produced in large quantities as a by-product of chemical pulping and cellulosic ethanol processes. Consequently, analytical methods are required to assess the content of valuable chemicals contained in these complex lignin wastes. This review is devoted to the application of mass spectrometry, including data analysis strategies, for the elemental and structural elucidation of lignin products. We describe and critically evaluate how these methods have contributed to progress and trends in the utilization of lignin in chemical synthesis, materials, energy, and geochemistry. 相似文献
28.
29.
Jianye Ge Benjamin Crysup Dixie Peters Romy Franco Muyi Liu Xuewen Wang Meng Huang Bruce Budowle 《Electrophoresis》2023,44(13-14):1080-1087
Y chromosome Short Tandem Repeat (STR) haplotypes have been used in assisting forensic investigations primarily for identification and male lineage determination. The current SWGDAM interpretation guidelines for Y-STR typing provide helpful guidance on those purposes but do not address the issue of kinship analysis with Y-STR haplotypes. Because of the high mutation rate of Y-STRs, there are complex missing person cases in which inconsistent Y-STR haplotypes between true paternal lineage relatives will arise and cases with two or more male references in the same lineage and yet differ in their haplotypes. Therefore, more useful methods are needed for interpreting the Y-STR haplotype data. Computational methods and interpretation guidelines have been developed specifically addressing this issue, either using a mismatch-based counting method or a pedigree likelihood ratio method. In this study, a software program, MPKin-YSTR, was developed by implementing those more sophisticated methods. This software should be able to improve the interpretation of complex cases with Y-STR haplotype evidence. Thus, more biological evidence will be interpreted, which in turn will result in more investigation leads to help solve crimes. 相似文献
30.
采用液相色谱-高分辨质谱技术对不同时间段斑马鱼体内ADB-BUTINACA的21种代谢产物进行分析。首先采用正交信号变换的偏最小二乘判别分析和层次聚类分析方法筛选出7种具有显著性差异的组间代谢物,以7种差异代谢物为特征建立Stacking集成学习模型,对4组不同时间段的斑马鱼体内样本进行分类预测。结果显示,模型预测准确率高达98%,表明筛选的潜在差异代谢物能够有效反映不同时间段原药在斑马鱼体内的变化情况;对7种潜在差异代谢物在4类样本体内的含量变化进行富集分析,结果表明差异代谢物的总体含量随着染毒时间的增加而降低,各类代谢物的含量分布由最初的不均衡趋向于均衡分布。此外,实验发现大部分差异代谢物的代谢路径与羟基化反应密切相关,推测原药在生物体内发生羟基化反应与给药时间推断方面具有一定关联性。实验结果可为药物服用时间推断等相关领域分析提供依据。 相似文献